Misaki Suzuhara

The main series character! and the best angelic layer player ^_^ Misaki is a polite, cute and friendly girl! She was living with her mother and father, well they aren't her real mother/father, anyway, she moved to Tokyo where she knows about the Angelic Layer!

 Misaki loves Angelic Layer for the 1st time she saw it! She saw two girls on like a huge TV on the road, she really liked one of the dolls who were so strong and it was blue, Misaki didn't know that the owner of that doll was her mother!  her first battle done by mistake! she wanted to take a ticket to rent an arena but she took a ticket to play!

 Misaki is really good in cooking, and very bad in sports @.@, everyone who eats her meals love it/them!

 Misaki could change many Angelic Layer players, wondering how? She actually when the players been mean or do some wrong things, she says that Angelic Layer is fun, and it won't be fun if we did wrong things....  Misaki's best friend, Tamayo, gave Misaki's new name which's "Misakichi"!

Hikaru

Hikaru is Misaki's doll! a fast type model. Hikaru is a real strong, fast, and beautiful doll! her  best attack called "The Rolling Thunder"!

Tamayo Kizaki

Super energetic girl! Tamayo! she usually hang out with Mizaki when she won, and she also fight with boys, and specially Kotaru, but with Kotaru.. she fights with him as a friend! she is the one who made a new name of Misaki, which's "Misakichi"! Tamayo doesn't have doll.

Hatoku Kobayasha

The young sister of Kotaru, a five years old girl, but one of the best Angelic Layer players! she could win continuously! and her she also know how to move her doll well. Without Hatoku, most of the first Misaki's battles won't Misaki's won in them without the words of Hatoku ^_^

Kotaru Kobayasha

A handsome boy that likes Angelic Layer, but he doesn't have one. He is in Misaki's class, he is kinda cold, but he is one of her best friends and who is mostly with her ^__^

Ringo/Seto-san

An Angelic Layer player and a popular singer too! Seto likes Misaki! and she wanted to be herself, and she did ^_^ since that Misaki could won on her! Seto is so funny girl, she usually run from her manager! because she gives her many jobs to do. 

Iccha/Chief Mihara

One of the most professional and knowledgeable Angelic Layer professors, he's somehow crazy sometimes! he likes surprising people. and he also likes to do some crazy stuff to his helper, Ogata, if he did wrong things, like, once, in the 1st episode, Ogata thought that Chief Mihara were caught in the police due doing some Hentai stuff.. looooool, then Mihara just took pranksters and put them on his jeans !! XD!!!

Shouko

Misaki's aunt, a TV broadcaster! ops! or as she want us to call her.. 'The Beautiful news broadcaster' ! well, i don't see that she is beautiful that much! Shouko-san lives in Tokyo, when Misaki came there, she lives with Shouko-san!

Shouko-san loves Misaki's meals a lot ! 

Misaki's Mom

The original Misaki's mom, she is actually one of the greatest Angelic Layer players, she didn't tell Misaki that she is her original mother, but i think at the end of the series she will/she did.